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Fumaryl chloride

Fumaryl chloride

CAS: 627-63-4

Molecular Formula: C4H2Cl2O2

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Fumaryl chloride - Names and Identifiers

Name Fumaryl chloride
Synonyms Fumaryl chloride
FUMARYL CHLORIDE
FUMAROYL DICHLORIDE
trans-Butenedioyl chloride
Dichlorid kyseliny fumarove
trans-2-Butenedioyl dichloride
CAS 627-63-4
EINECS 211-005-4
InChIKey ZLYYJUJDFKGVKB-OWOJBTEDSA-N

Fumaryl chloride - Physico-chemical Properties

Molecular FormulaC4H2Cl2O2
Molar Mass152.96
Density1.415 g/mL at 25 °C(lit.)
Melting Point-2 °C
Boling Point161-164 °C(lit.)
Flash Point165 °F
Water Solubilitydecomposes
AppearanceForm Liquid, color Clear yellow
Storage Condition2-8°C
StabilityMoisture Sensitive
Refractive Indexn20/D 1.499(lit.)
Physical and Chemical PropertiesChemical properties pale yellow liquid. Boiling point 158-160 ℃,63 ℃(1.68kPa), relative density 1.408(20 ℃), refractive index 1.5004(18 ℃), flash point 73 ℃.
UseUses for organic synthesis, highly reactive organic intermediates.

Fumaryl chloride - Risk and Safety

Hazard SymbolsC - Corrosive
Corrosive
Risk CodesR20/21/22 - Harmful by inhalation, in contact with skin and if swallowed.
R34 - Causes burns
R37 - Irritating to the respiratory system
R29 - Contact with water liberates toxic gas
R36/37 - Irritating to eyes and respiratory system.
R14 - Reacts violently with water
Safety DescriptionS26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection.
S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S8 - Keep container dry.
S27 - Take off immediately all contaminated clothing.
UN IDsUN 1780 8/PG 2
WGK Germany3
RTECSLT2800000
FLUKA BRAND F CODES21
TSCAYes
HS Code29171990
Hazard Class8
Packing GroupII

Fumaryl chloride - Upstream Downstream Industry

Raw MaterialsThionyl chloride
Phosphorus pentachloride
Zinc chloride
Maleic anhydride
Fumaric acid
Phthaloyl dichloride
Downstream ProductsTRANS-1,2-DIBENZOYLETHYLENE
2,4-DIBROMOMESITYLENE

Fumaryl chloride - Nature

Specific gravity 1.415 (20/4℃)
BRN 1721342
NIST chemical information Fumaryl chloride(627-63-4)
EPA chemical information 2-Butenedioyl dichloride, (2E)- (627-63-4)
Last Update:2024-04-10 22:29:15

Fumaryl chloride - Production method

It is obtained by the reaction of maleic anhydride and phthaloyl chloride in the presence of zinc chloride. Heat maleic anhydride, industrial phthalic chloride and anhydrous zinc chloride at 130-135 ℃ for 2 hours, and pay attention to avoid overheating. Then it is cooled to 90-95 ℃, and distilled quickly. The 62-64(1.73kPa) fraction is collected as trans-butene diacyl chloride with a yield of about 90%. In addition, trans-butene diacyl chloride can also be prepared by reacting fumaric acid with phthalyl chloride or thionyl chloride or phosphorus pentachloride.

Last Update:2024-04-10 22:29:15
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Mobile: 18916960931
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View History
Fumaryl chloride
Raw Materials for Fumaryl chloride
Thionyl chloride
Phosphorus pentachloride
Zinc chloride
Maleic anhydride
Fumaric acid
Phthaloyl dichloride
Downstream Products for Fumaryl chloride
TRANS-1,2-DIBENZOYLETHYLENE
2,4-DIBROMOMESITYLENE
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